The black tie do - raising funds in aid of the Sports For Peace initiative - is to be held at the Victoria & Albert Museum and will feature a champagne reception and 4-course dinner.
'Forget the official opening ceremony, this is the party to be at,' says a source.
'It's going to be an Olympics-themed party, with huge buckets of homemade cocktails on offer.'
The couple, who are hosting the event in honour of boxing legend Muhammed Ali, have drawn up an invite list that reportedly includes Prince William and brother Harry plus David and Victoria Beckham.
'The who's who of British and American celebrity will be in attendance,' the source tells the Daily Mirror.
Invitees have been ordered not to take any photos from their phones.
Brad, 48, and his fiancée have temporarily set up home in the UK while Angelina, 37, films her new movie Maleficient.
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